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About the book:
Publisher: Woodhead Publishing
Authors: Fernando Pacheco-Torgal & 2 more.
Place of Publication: United Kingdom
Pages: 333
Edition: 2022
Language: English
Size: 19Mb
This exceptional new book is organized into four main sections, each of which relates to a vital area of research: indoor environment toxicity, fire toxicity, radioactive materials, and toxicity caused by plastics, metals, asbestos, nanoparticles, and construction waste. It features critical chapters on a variety of topics, such as reducing chemical emissions in homes by using eco-labeled building materials, examining the potential risks of nano-enabled construction products, assessing the toxicity of concrete that contains hazardous waste, and exploring the immobilization of toxic waste in geopolymers. Furthermore, the book provides insights into the management of hazardous substances in the circular economy.
As a result, it is an indispensable reference for academic and industrial researchers, materials scientists, civil engineers, architects, fire safety engineers, postgraduate students, contractors, and other professionals who work or have an interest in the field of building material toxicity.
Content:
List of contributors xi
1 Introduction to advances in the toxicity of construction and building materials 1
Fernando Pacheco-Torgal
1.1 COVID-19, the toxicity of construction and building materials and the need for healthy built environments 1
1.2 Outline of the book 4
References 6
PART I Indoor Air Contaminants 9
2 Assessment of hazardous compounds in building materials accumulated by the action of the atmospheric pollution 11
Nagore Prieto-Taboada, Gorka Arana and Juan Manuel Madariaga
2.1 Atmospheric pollution and building materials: general knowledge 11
2.2 Urban-industrial buildings 14
2.3 Analysis of hazardous pollutant in building materials 16
2.3.1 Spectroscopic techniques for nondestructive analysis 17
2.3.2 Quantitative analysis of the accumulated pollutants 19
2.4 Conclusion 25
Acknowledgment 26
References 26
3 Toxicity of semivolatile organic compounds 33
Kenichi Azuma and Hideto Jinno
3.1 Semivolatile organic compounds in indoor environments 33
3.2 The emission of semivolatile organic compounds from building materials and consumer products 35
3.3 Exposure to semivolatile organic compounds emitted from building materials and consumer products 36
3.4 Health risk from exposure to semivolatile organic compounds 38
3.4.1 Multiroute and multimedia exposure (that is, aggregate exposure) to semivolatile organic compounds 40
3.4.2 Multiple exposure (that is, combined exposure) to indoor pollutants and the combined health effects 44
3.5 Conclusions and recommendations 49
References 49
4 Volatile organic compound emissions in building materials 55
Xiaojun Zhou
4.1 Volatile organic compound emission model of building materials 55
4.1.1 Single-phase mass transfer model 55
4.1.2 Porous media mass transfer model 59
4.2 VOC emission characteristic parameters of building materials 61
4.2.1 The diffusion coefficient 61
4.2.2 The partition coefficient 63
4.2.3 The initial emittable concentration 65
4.2.4 Multiparameter experimental measurement method 68
4.3 The control methods of building materials VOC emissions 69
4.3.1 Air purification 70
4.3.2 Dilution ventilation 70
4.3.3 Source control 71
4.4 Conclusion 73
References 73
Further reading 77
PART II Fire Toxicity of Building Materials 79
5 Toxicity of toxic gases emitted during a fire and ventilation 81
Jerzy Andrzej Gałaj and Damian Saleta
5.1 Introduction 81
5.2 Toxicity of products emitted during fire and hazard to humans 84
5.2.1 General information 84
5.2.2 Parameters for assessing the toxicity of decomposition and combustion products 84
5.2.3 The impact of toxic gases emitted during a fire on humans 87
5.3 Impact of ventilation on the toxicity of the fire environment 90
5.3.1 Theoretical background 90
5.3.2 Results of fire experiments 95
5.4 Conclusions and final remarks 112
References 113
6 Flame-retardant wood plastic composites 117
Chunxiang Ding and De-Yi Wang
6.1 Introduction 117
6.2 Combustion process of wood plastic composites 118
6.3 Fire retardant chemicals in wood plastic composites 119
6.3.1 Metal-containing compounds 119
6.3.2 Phosphorus-containing compounds 120
6.3.3 Boron-containing compounds 121
6.3.4 Silicon-containing compounds 123
6.3.5 Carbon-containing compounds 126
6.3.6 Other treatments 129
6.4 Conclusion 131
References 132
7 Fire behavior of sandwich panels with different cores 137
Maciej Celi ´ nski, Kamila Sałasi ´ nska, Kamila Mizera and
Paweł Kozikowski
7.1 Introduction: construction of sandwich panels 137
7.1.1 Steel sheets and coating 137
7.1.2 Core types 138
7.1.3 Thermal conductivity of sandwich panels 140
7.2 Thermal stability and flammability of sandwich panels 142
7.2.1 Thermal stability 143
7.2.2 Burning behavior of sandwich panel cores 153
7.3 Flame retardants 162
7.4 Concluding remarks 166
Acknowledgments 167
References 167
8 Natural radioactivity in cement 171
Semih Nemlioglu, Naim Sezgin and Bilge Ozdogan Cumali
8.1 Natural radioactivity and sources 171
8.2 Cement 173
8.2.1 Raw materials and production process 174
8.2.2 Cement classification 175
8.3 Natural radioactivity of cement and cement raw materials 177
8.3.1 Natural radionuclides activity and radiological parameters 178
8.4 Results and discussion 181
8.4.1 Radionuclides activity and calculated radiological parameters in cement raw materials 181
8.4.2 Radionuclides activity and radiological parameters in cement types 189
8.5 Conclusion 190
References 201
Further reading 206
9 Coal bottom ash natural radioactivity in building materials 207
Miguel A´ngel Sanjua´n
9.1 Introduction 207
9.2 Coal as source of ashes 209
9.3 Coal bottom ash as constituent of construction materials 211
9.4 Coal bottom ash as sand replacement in concrete 212
9.5 Coal bottom ash as pozzolanic addition in Portland cement 212
9.6 Radioactivity in building materials made with coal bottom ash 213
9.7 Conclusion 218
References 219
Further reading 224
10 Recycling of radioactive phosphogypsum wastes 225
Yelizaveta Chernysh
10.1 Introduction: environmental problems of phosphogypsum accumulation 225
10.2 Composition of phosphogypsum of different genesis and its physical and chemical characteristics 226
10.2.1 Effect of phosphates on the properties of the binder 226
10.2.2 Effect of fluorine compounds on the properties of the binder 226
10.2.3 Effect of radiation contamination of phosphogypsum 228
10.3 Current trends in phosphogypsum waste management processes 229
10.4 Visualization of clusters of directions in phosphogypsum waste management 232
References 237
PART III Toxicity of Metals, Asbestos and of Waste Reuse 241
11 Lead-based construction and building materials: human exposure, risk, and risk control 243
Shakhawat Chowdhury
11.1 Introduction 243
11.2 Lead exposure 243
11.3 Lead toxicity 244
11.4 Methodology for risk assessment of lead exposure 245
11.4.1 Identification of lead-based construction and building materials 246
11.4.2 Exposure analysis 246
11.4.3 Risk characterization 247
11.5 Results and discussions 249
11.5.1 Lead-based construction and building materials 249
11.5.2 Exposure and risk characterization 251
11.6 Conclusions 254
Acknowledgments 255
References 255
12 Demolition waste contaminated with asbestos 261
Nadezda Stevulova, Adriana Estokova, Marian Holub and Eva Singovszka
12.1 Introduction 261
12.2 Predemolition audit 262
12.3 Asbestos material present in the building materials 262
12.3.1 Asbestos properties 262
12.3.2 Asbestos-cement materials and products 263
12.3.3 Methods for detecting of the asbestos 264
12.4 Risk of asbestos dust during reconstruction and demolition 265
12.4.1 Health effects and toxicity of asbestos fibers 265
12.4.2 Monitoring the airborne asbestos concentrations and exposure limit 268
12.5 Case study 269
12.5.1 Process of removal the asbestos-cement materials 269
12.5.2 Characterization of asbestos demolition waste 270
12.5.3 Monitoring of airborne asbestos particles indoors during deconstruction of ACMs 271
12.6 Conclusion 277
References 277
13 Recycling and reuse of bottom ashes from municipal solid-waste incineration plants in building materials 285
Adriano Michael Bernardin
13.1 Introduction 285
13.2 Characteristics of ashes from the combustion of municipal solid wastes 286
13.3 Waste to energy and recovery of valuable metals from municipal solid-waste incineration bottom ashes 289
13.4 Toxicity of municipal solid-waste incineration bottom ashes 289
13.5 Recycling and reuse of municipal solid-waste incineration bottom ashes in building materials 291
13.5.1 Replacement of ordinary Portland cement in mortars and concretes 291
13.5.2 Production of synthetic and lightweight aggregates 292
13.5.3 Cement mixes and asphalt concretes for road pavements 292
13.5.4 3D printable concretes 293
13.5.5 Filling material for geotextiles 293
13.5.6 Synthesis of mesoporous silica 293
13.5.7 Manufacturing of ceramic tiles and glasses 293
13.5.8 Alkali-activated materials 294
13.6 Future trends on the use of municipal solid-waste incineration bottom ashes in Europe 294
13.7 Final remarks 295
References 295
14 Leaching of concrete with mine tailings 299
Obinna Onuaguluchi, Shubham Jain and Nemkumar Banthia
14.1 Introduction 299
14.1.1 Background 299
14.2 Overview of mine tailings characteristics 300
14.3 Overview of leaching mechanisms and leaching test methods 304
14.3.1 Background on the leaching mechanisms 305
14.3.2 Leaching test methods 305
14.4 Toxic metal immobilization mechanisms in cement and alkali-activated matrices 312
14.5 Factors influencing the leaching of toxic metals from cement composites 316
14.5.1 Matrix microstructure 316
14.5.2 Exposure environment 316
14.5.3 Surface-to-volume ratio 317
14.6 Long-term durability related concerns for mine tailings-blended composites 317
14.7 Conclusions 320
References 320
Index 329